Tetrahedron p. 8881 - 8886 (1997)
Update date:2022-08-05
Topics:
Josien, Hubert
Curran, Dennis P.
(S)-Mappicine (2) and mappicine ketone (1) have been prepared from methylacetoacetate (4) by a strategy featuring a radical cascade reaction of an isonitrile as the key step. The introduction of the hydroxy group of (S)- mappicine occurred with moderate selectivity through asymmetric hydroxylation.
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Doi:10.1016/j.tet.2004.07.092
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(1997)
