Reactions of FeIII with LiAlH4 and LiBH4 in the presence of bis(diphenylphosphino)methane (dppm) and CO. The crystal and molecular structures of trans-[Fe(Cl)(CO)(η2-dppm)2] [FeCl4], trans-

DOI: 10.1016/S0277-5387(97)00025-9

Source and publish data:

Polyhedron p. 2797 - 2807 (1997)

Update date:2022-08-04

Topics:

Authors:

Gao, Yuan

Holah, David G.

Hughes, Alan N.

Spivak, Greg J.

Havighurst, Matthew D.

Magnuson, Vincent R.

Polyakov, Valery

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Article abstract of DOI:10.1016/S0277-5387(97)00025-9

Reactions between Fe^III, dppm, CO as appropriate and LiAlH₄ produce the Fe^II complexes trans-[Fe(Cl)(CO)(η²-dppm)₂][FeCl₄]. (1a) trans-[Fe(H)₂(η²-dppm)₂] (2

Full text of DOI:10.1016/S0277-5387(97)00025-9

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Product name:[Fe(CO)3((C₆H₅)2PCH₂P(C₆H₅)2)2]

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