Journal of Organometallic Chemistry p. 77 - 79 (1997)
Update date:2022-08-03
Topics:
Scheffknecht, Christoph
Peringer, Paul
Pd(pp2) (O3SCF3)2 (pp2 = bis(2-diphenylphosphinoethyl)phenylphosphine) catalyses the transformation of non-activated terminal alkynes into acetals. The reaction proceeds fast, without the addition of heat and in quantitative yield. σ-Alkynyl-palladium complexes have been identified as intermediates.
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(1952)Doi:10.1055/s-1997-3271
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(1997)
