Palladium-catalysed mild transformation of non-activated terminal alkynes into acetals 1

DOI: 10.1016/S0022-328X(96)06955-0

Source and publish data:

Journal of Organometallic Chemistry p. 77 - 79 (1997)

Update date:2022-08-03

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Authors:

Scheffknecht, Christoph

Peringer, Paul

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Article abstract of DOI:10.1016/S0022-328X(96)06955-0

Pd(pp₂) (O₃SCF₃)₂ (pp₂ = bis(2-diphenylphosphinoethyl)phenylphosphine) catalyses the transformation of non-activated terminal alkynes into acetals. The reaction proceeds fast, without the addition of heat and in quantitative yield. σ-Alkynyl-palladium complexes have been identified as intermediates.

Full text of DOI:10.1016/S0022-328X(96)06955-0

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