SOLVOLYTIC STUDIES OF THE HIGHLY CROWDED 1-ARYL-1-PHENYL-1-(TRIFLUOROMETHYL)METHYL BR0MIDE AND TOSYLATES

DOI: 10.1016/S0040-4039(01)80816-9

Source and publish data:

Tetrahedron Letters p. 355 - 358 (1985)

Update date:2022-08-02

Topics:

Authors:

Liu, Kwang-Ting

Kuo, Mann-Yan

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Article abstract of DOI:10.1016/S0040-4039(01)80816-9

In the titled system the remarkably high tosylate/bromide solvolysis rate ratio of 1.56E6:1 indicates a highly strained ground state, and the reverse order of reactivity for substrate having l-(4-trifluoromethyl)phenyl vs. that having 1-(3-trifluoromethyl

Full text of DOI:10.1016/S0040-4039(01)80816-9

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