Tetrahedron Letters p. 5445 - 5448 (1997)
Update date:2022-08-05
Topics:
Liu, Ping
Celatka, Cassandra A.
Panek, James S.
The synthesis of the fully functionalized tris-oxazole fragment 9 found in marine metabolites kabiramide C and halichondramide is reported employing modified Hantzsch methodology. Starting with the condensation reaction between cinnamamide 1 and ethyl bromopyruvate 2, the synthetic sequence leading to 9 was carried out in 13 steps with an overall yield of 26%.
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