Tetrahedron Asymmetry p. 3101 - 3106 (1997)
Update date:2022-08-05
Topics:
Tanikaga, Rikuhei
Obata, Yukinori
Kawamoto, Ken-Ichi
Baker's yeast-mediated reduction of 3-(nitromethyl)-, 3-(phenylsulfonyl)-, and 3-[(phenylsulfonyl)methyl]-cyclohexanones 1a,c,d led to the delivery of a hydride to the re-face of the prochiral ketones to provide cyclohexanols (1S,3S)- and (1S,3R)-2a,c,d with high enantioselectivities in good yields. The remote nitro and sulfonyl groups, in contrast to alkyl and sulfenyl groups, may play an important role in binding to an enzyme.
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Doi:10.1016/S0031-9422(00)84961-4
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(1996)Doi:10.1016/s0020-1693(97)05656-9
(1997)
