Canadian Journal of Chemistry p. 1136 - 1150 (1997)
Update date:2022-09-26
Topics:
Kutney, James P.
Cirera, Carles
The development of a new synthetic approach to (-)-Ambrox (37) and epi-Ambrox (29) using thujone (1) as a chiral synthon, is presented. Thujone (1), a readily available starting material obtained from Western red cedar, can be efficiently converted to β-cyperone (2) and the latter is then chemically elaborated to the key intermediate, the enone 6. A carbonyl transposition of 6 to enone 9 also allows a formal synthesis of (-)-Polywood (18).
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