Lanthanide catalysts for the hetero Diels-Alder reaction: Effect of ligand structure and acidity

DOI: 10.1139/v97-125

Source and publish data:

Canadian Journal of Chemistry p. 1047 - 1054 (1997)

Update date:2022-08-05

Topics: Acid strength Chelating Ligands Steric and Electronic Effects

Authors:

Spine Spine

Clouston

Berg Berg

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Article abstract of DOI:10.1139/v97-125

A series of yttrium, ytterbium, and lanthanum hexa- or heptacoordinate complexes were prepared and their catalytic activities tested in the hetero Diels-Alder reaction between crotonaldehyde and ethyl vinyl ether. It was found that a pK_a below

Full text of DOI:10.1139/v97-125

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