Intramolecular Diels-Alder Reactions of Thio-Substituted Dienes with Enones

DOI: 10.1002/jccs.199700055

Source and publish data:

Journal of the Chinese Chemical Society p. 373 - 378 (1997)

Update date:2022-08-03

Topics:

Authors:

Chou, Shang-Shing P.

Yu, Yu-Ju

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Article abstract of DOI:10.1002/jccs.199700055

Thio-substituted dienes bearing an enone moiety were readily prepared from 3-sulfolenes, and their intramolecular Diels-Alder (IMDA) reactions were studied. Octahydronaphthalenones were produced in good yield with high stereoselectivity. Hexahydroindenones were also obtained, but the stereoselectivity was lower.

Full text of DOI:10.1002/jccs.199700055

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