Tetrahedron Asymmetry p. 2933 - 2937 (1997)
Update date:2022-08-03
Topics:
Katagiri, Toshimasa
Ihara, Hideki
Takahashi, Mikihiro
Kashino, Setsuo
Furuhashi, Keizo
Uneyama, Kenji
We have succeeded in intramolecular nucleophilic substitution of the hydroxyl group in (S)-1-(alkylamino)-3,3,3-trifluoro-2-propanol. The reaction provides an optically pure (R)-1-benzyl-2-trifluoromethylaziridine in good yield from optically pure (S)-3-(benzylamino)-1,1,1-trifluoro-2-propanol which was prepared from (S)-3,3,3-trifluoropropene oxide (75% ee).
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Doi:10.1007/BF02153757
(1968)Doi:10.1016/S0040-4020(97)01053-3
(1997)Doi:10.1021/acs.orglett.6b02642
(2016)Doi:10.1055/s-0037-1610005
(2018)Doi:10.1039/b814598a
(2008)Doi:10.1016/j.ejmech.2006.12.008
(2007)