Phosphoraneiminato complexes of boron. Syntheses and crystal structures

DOI: 10.1002/zaac.19976231016

Source and publish data:

Zeitschrift fur Anorganische und Allgemeine Chemie p. 1567 - 1576 (1997)

Update date:2022-08-05

Topics:

Authors:

M?hlen M?hlen

Neumüller

Faza Faza

Müller Müller

Massa Massa

Dehnicke

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1002/zaac.19976231016

The bromoderivatives of the title compounds are prepared from the corresponding silylated phosphoraneimines Me₃SiNPR₃ and boron tribromide. The boron subcompound [{B₂(NMe₂)₂.₂(NPEt₃) ₂]Cl₂ derives from Me₃SiNPEt₃ and B₂Cl₂(NMe₂)₂. All complexes are characterized by NMR and IR spectroscopy as well as by crystal structure determinations. [BBr₂(NPMe₃)]₂ (1): Space group P2₁/n, Z = 2, R = 0.031. Lattice dimensions at -50°C: a = 723.8, b = 894.2, c = 1305.4 pm, β = 92.35°. 1 forms centrosymmetric molecules.

Full text of DOI:10.1002/zaac.19976231016

Products guided by the article

Product name:[B₂Br₂(NP(C₆H₅)3)3]⁽¹⁺⁾*BBr₄^(1-)=[B₂Br₂(NP(C₆H₅)3)3]BBr₄

Cas No:198135-61-4

R&D Labs maybe for 198135-61-4

Alway Chem, China

website:http://www.alwaychem.com

Contact:+86-532-8586-4000, 8586-5000

Address:NO.51, TAIPING ROAD, QINGDAO, CHINA. 266001
NanJing Rate Biochemicals CO., LTD

Contact:+86-25-84931986

Address:NO. 1 Hongjing Road,Jiangning Science Park,Nanjing,China
Hangzhou Haiqiang Chemical Co.,Ltd.

Contact:+86-571-86960370

Address:Add: 5/F, Around Town North Road,No. 10, Hangzhou, Zhejiang,China
Shanghai Massive Chemical Technology Co., Ltd.

website:http://www.massivechem.com/

Contact:+86 21 34943721

Address:Room 435, 4th floor, Building 9, No. 2568 Gudai Road,Minhang District, Shanghai,
Puyang Willing Chemicals Co.,Ltd.

Contact:86-393-4840366

Address:Puyang Henan China

Relevant to this article

Doi:10.1021/ja01290a100
(1937)
Synthesis of 7-methoxybenzolactam-V8 using aminomercuration as a key reaction

Doi:10.1016/S0040-4039(01)00747-X
(2001)
Bioactive iridoids and a new lignan from Allamanda cathartica and Himatanthus fallax from the suriname rainforest

Doi:10.1021/np970253e
(1997)
Synthesis, spectroscopic and redox properties of ruthenium complexes with selenoether macrocycles: Crystal structures of cis-[RuCl₂([16]aneSe₄)] and trans-[RuCl(PPh3)([16]aneSe₄)]PF₆ ([16]aneSe₄ = 1,5,9,13-tetraselenacyclohexadecane)

Doi:10.1039/a703667a
(1997)
Synthesis, structure and catecholase activity study of dinuclear copper(II) complexes

Doi:10.1039/a704245k
(1997)
Synthesis and configurational analysis of dl-myxoviromycin.

Doi:10.1248/cpb.16.232
(1968)

Article Doi