Chemistry Letters p. 1901 - 1904 (1991)
Update date:2022-08-04
Topics:
Mukaiyama, Teruaki
Shiina, Isamu
Kobayashi, Shu
syn-α,β-Dihydroxy thioesters are prepared in good yields with high diastereo- and enantioselectivities by the asymmetric aldol reaction of 1-trimethylsiloxy-1-ethylthio-2-t-butyldimethylsiloxyethene with aldehydes using a chiral promoter consisting of tin(II) triflate, a chiral diamine and dibutyltin diacetate.
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