Tetrahedron p. 13945 - 13958 (1997)
Update date:2022-07-29
Topics:
Abdou, Wafaa M.
Salem, Monier A. E.
Sediek, Ashraf A.
The reaction of p-quinone 1 with ylides 2a and 2b afforded the corresponding phosphonium salts 8a,b, p-quinone-dimethanides 4a,b(Z) and 5a,b(E); substituted phenols 7a,b(Z and E) and coumarin-derivative 11 (only with 2a). The reaction of 1 with ylide 2c gave, besides 4c, 5c and 8c, hydroquinone[1]cyclobutene 16 and the Diels-Alder product 17. Reactions of 1 with 2d and 3 (salts) in the presence of sodium alkoxide yielded through preferred attack on the nitrile function, azo-22 and bisimino-24 compounds, respectively.
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Doi:10.1016/S0040-4020(97)10066-7
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