5,6,11,12,17,18-hexadehydro-1,4,7,10,13,16-hexaethynyltribenzo[a,e,i]cyclodod ecene: Synthesis and CpCO-catalyzed cycloisomerization to the first superdelocalized oligophenylenes

DOI: 10.1002/anie.199721031

Source and publish data:

Angewandte Chemie - International Edition in English p. 2103 - 2108 (1997)

Update date:2022-08-05

Topics: Purification and characterization Synthesis of the Precursor Compound

Authors:

Eickmeier

Junga Junga

Matzger Matzger

Scherhag

Shim Shim

Peter Peter

Vollhardt

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Article abstract of DOI:10.1002/anie.199721031

The largest subunit of the carbon allotrope 'graphyne', title compound 1, is also a potential precursor to circular [6]phenylene, antikekulene. Single and double CpCo-catalyzed cycloisomerization provided the respective angular [3]- and [5]-phenylenes. Th

Full text of DOI:10.1002/anie.199721031

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