
Tetrahedron p. 16029 - 16040 (1997)
Update date:2022-08-03
Topics:
Ishihara, Jun
Sugimoto, Tetsuya
Murai, Akio
An asymmetric synthesis of syringolide 1, one of the elicitors produced by Pseudomonas syringae pv. tomato, is described. It was synthesized from 2- (t-oxocthyl)-2-buten-4-olide via 1,4-addition of alkenyl cuprate, asymmetric dihydroxylation, and intramolecular Michael reaction.
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