A novel enantioselective synthesis of (+)-myriocin based on the chemistry of 1-trimethylsilylbuta-2,3-dienes

DOI: 10.1016/S0040-4039(97)10077-6

Source and publish data:

Tetrahedron Letters p. 7887 - 7890 (1997)

Update date:2022-08-03

Topics:

Authors:

Hatakeyama, Susumi

Yoshida, Masashi

Esumi, Tomoyuki

Iwabuchi, Yoshiharu

Irie, Hiroshi

Kawamoto, Toshiki

Yamada, Hidetoshi

Nishizawa, Mugio

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Article abstract of DOI:10.1016/S0040-4039(97)10077-6

A synthesis of (+)-myriocin has been achieved in a highly stereoselective manner employing TiCl₄ catalyzed addition of 1- trimethylsilylbuta-2,3-diene to an aldehyde and Et₂AICI catalysed cyclization of an epoxytrichloroacetimidate f

Full text of DOI:10.1016/S0040-4039(97)10077-6

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