NUCLEOPHILIC SUBSTITUTION IN ORGANOMERCURY HALIDES BY A FREE RADICAL CHAIN PROCESS

DOI: 10.1016/S0022-328X(00)86809-6

Source and publish data:

Journal of Organometallic Chemistry p. 43 - 56 (1982)

Update date:2022-08-05

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Authors:

Russel, Glen A.

Hershberger, James

Owens, Karen

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Article abstract of DOI:10.1016/S0022-328X(00)86809-6

Primary and secondary alkylmercury halides react with the salts of secondary nitroalkanes to afford tertiary nitroalkanes, mercury metal, and halide ion.The reaction is light initiated and is strongly inhibited by radical scavengers.Cyclized products resu

Full text of DOI:10.1016/S0022-328X(00)86809-6

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