Silica gel-catalyzed β-O-glucosylation of alcohols with 1,2-anhydro-3,4,6-tri-O-pivaloyl-α-D-glucopyranose

DOI: 10.1016/S0040-4039(97)10315-X

Source and publish data:

Tetrahedron Letters p. 8709 - 8712 (1997)

Update date:2022-07-29

Topics:

Authors:

Matsushita, Yoh-Ichi

Sugamoto, Kazuhiro

Kita, Yoshio

Matsui, Takanao

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Article abstract of DOI:10.1016/S0040-4039(97)10315-X

1,2-Anhydro-3,4,6-tri-O-pivaloyl-α-D-glucopyranose (1a) was allowed to react with alcohols in the presence of solid acids such as silica gel and zeolite HY, to afford β-O-glucosides stereoselectively. Several natural glucosides were synthesized by the application of the present resection.

Full text of DOI:10.1016/S0040-4039(97)10315-X

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