Tetrahedron Letters p. 8529 - 8532 (1997)
Update date:2022-08-03
Topics:
Shimizu, Toshio
Sakamaki, Kensuke
Kamigata, Nobumasa
Reactions of Ph2C3 dianion with alkyl thiocyanates or ethylene 1,2-dithiocyanate give 1,3-bis(alkylthio)allenes or tetrathiacyclic bisallene, respectively. Thermal reactions of 1,3-bis(benzylthio)allene and tetrathiacyclic bisallene afford 2,3,5-triphenylthiophene and 1,2-bismethylidene cyclobutane derivatives, respectively.
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