Tetrahedron p. 8793 - 8808 (1994)
Update date:2022-08-03
Topics:
Bury, Paul
Hareau, Georges
Kocienski, Philip
Dhanak, Dashyant
Two approaches to the sesterterpenoid phospholipase A2 inhibitors seco-manoalide (3) and manoalide (1) are described based on carbometallation of propargylic alcohols to generate the functionalised C6-C7 trisubstituted alkene.Both syntheses also deploy the photooxidation of a furan in order to generate a 4-substituted 5-hydroxy-2(5H)-furanone moiety.
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Doi:10.1007/BF02291936
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