Tetrahedron p. 17449 - 17460 (1997)
Update date:2022-07-30
Topics:
Bergmann, David J.
Campi, Eva M.
Jackson, W. Roy
McCubbin, Quentin J.
Patti, Antonio F.
The rhodium catalysed reactions of N-alkenyl-1,3-diaminopropanes with H2/CO usually give mixtures of diazabicycloalkanes and aminopropyl lactams. The chemo- and regioselectivity of these reactions are influenced by the choice of ligand and by the ratio of H2 and CO in the gas mixture and in some cases formation of a single compound can be achieved.
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Doi:10.1246/bcsj.41.1046
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(1997)
