Journal of Organometallic Chemistry p. 581 - 585 (1997)
Update date:2022-07-30
Topics:
Davies, David L.
Fawcett, John
Krafczyk, Roland
Russell, David R.
The Schiff bases (LL′) formed from pyridine-2-carboxaldehyde or 2-acetyl pyridine and S-1-phenylethylamine react with [Ru(mes)Cl2]2 (mes = η6-C6H3Me3-1,3,5) to form diastereomeric salts [Ru(mes)Cl(LL′)][BF4]. Crystallisation gives a single diastereomer, (SRuSC) in each case, which have been characterised by X-ray diffraction; the conformation of the phenylethyl group is different to related η6-benzene complexes. The configuration at the metal is solvent dependent, it is stable in CDCl3 but epimerisation occurs in D2O.
Nantong LiKai Chemical Co.,Ltd
Contact:+86-513-89068669
Address:Jincheng Science Park
Shandong General Materials Co.,Ltd（Shandong Aoertong Chemical Co., Ltd）
Contact:86-531-88072280
Address:No. 1825 Hualong Road, Licheng District, Jinan, Shandong, China
Shanghai Sunwise Chemical Co., Ltd
website:http://www.sunwisechem.com
Contact:86-021-33883180
Address:Room 10E, Building G, Westlink Center, No. 2337 Gudai Road, Minhang District, Shanghai, China PC: 201100
website:http://www.apeptides.com/en/
Contact:+86-21-60871011
Address:No. 80 Chuanshan Shuyuan Steet,Pudong,Shanghai
zhengzhou Triz Pharma-Tech Co., Ltd
website:http://www.Trizpharma-tech.com
Contact:+86-0371-86597269，53392065
Address:High-tech Industrial Development Zone, Zhengzhou City, NO.7 Holly Street
Doi:10.1016/S0223-5234(97)82775-4
(1997)Doi:10.1055/s-1998-1596
(1998)Doi:10.1139/v68-175
(1968)Doi:10.1021/jo9721251
(1998)Doi:10.1081/SCC-120013751
(2002)Doi:10.1016/S0022-328X(97)00188-5
(1998)
