Tetrahedron Letters p. 9009 - 9012 (1997)
Update date:2022-08-03
Topics:
Ito, Hisanaka
Matsumoto, Miyoko
Yoshizawa, Takeshi
Takao, Ken-Ichi
Kobayashi, Susumu
Stereoselective preparation of a structurally simplified 3,4-unsubstituted zaragozic acid derivative was achieved starting from D-glucose. The present approach involved the stereoselective addition of a vinyl Grignard reagent, selective cleavage of 1,2-diol, and regioselective acylation of the hydroxyl group at C-6.
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