Chemistry Letters p. 153 - 154 (1998)
Update date:2022-09-26
Topics:
Sawada, Hideo
Kurachi, Minaka
Kawase, Tokuzo
Takishita, Katsuhisa
Tanedani, Toshiyuki
Aoshima, Kazuyoshi
A new bis(perfluorocyclohexane carbonyl) peroxide was prepared by the reaction of the corresponding acyl fluoride and hydrogen peroxide. This peroxide was applicable for the direct introduction of perfluorocyclohexyl group into various organic molecules such as acrylic acid oligomer, benzene and polystyrene; in particular interest, not only equatorial but also axial conformational isomers were isolated in phenylperfluorocyclohexane thus obtained.
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