Chemistry Letters p. 119 - 120 (1998)
Update date:2022-08-03
Topics:
Ishii, Akihiro
Miyamoto, Fumie
Higashiyama, Kimio
Mikami, Koichi
The asymmetric synthesis of 1-substituted 2,2,2-trifluoroethylamines from chiral 1,3-oxazolidines having trifluoromethyl group derived from trifluoromethyl ketones and (R)-phenylglycinol is described. The stereospecific reduction of chiral 1,3-oxazolidines with LiAlH4 proceeds in retention fashion.
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