Tetrahedron Letters p. 543 - 546 (1998)
Update date:2022-08-04
Topics:
Pinchart, Alain
Dallaire, Carol
Gingras, Marc
Molecular wires containing p-phenylene sulfide units were synthesized. They could be used in material sciences and in supramolecular chemistry. Wires having 2 to 6 phenyl rings were functionalized at one end by an SH or SMe group, and at the other end, by an OH, OMe or OiPr groups. Formation of Ar-S bonds in the chain was achieved by Pd- or Cu-catalyzed couplings of aromatic thiols with aromatic halides. Conditions for a clean chemoselective deprotection of thiols from thiomethyl groups were developed.
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Doi:10.1016/S0040-4039(98)00194-4
(1998)Doi:10.1021/ja01146a015
(1951)Doi:10.1021/jo9622901
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(1958)Doi:10.1002/ejoc.202000737
(2020)Doi:10.1016/S0960-894X(98)00049-3
(1998)
