Synthesis of 6-thiosialic acids

DOI: 10.1016/S0040-4020(98)00167-7

Source and publish data:

Tetrahedron p. 4521 - 4538 (1998)

Update date:2022-09-26

Topics:

Authors:

Mack, Hans

Brossmer, Reinhard

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Article abstract of DOI:10.1016/S0040-4020(98)00167-7

The synthesis of 2-acetamido-2-deoxy-3-thio-D-mannose (11) is described. Chain elongation of thiazoline 10 with potassium-di-O-butyl-oxaloacetate yields epimeric 6-thiosialic acids 14 and 15. Chain extension of 18 with oxaloacetate/Ni⁺⁺ results

Full text of DOI:10.1016/S0040-4020(98)00167-7

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