Bioorganic and Medicinal Chemistry Letters p. 647 - 652 (1998)
Update date:2022-08-03
Topics:
Sawa, Masaaki
Imaeda, Yasuhiro
Hiratake, Jun
Fujii, Ryota
Umeshita, Ritsuko
Watanabe, Mitsuo
Kondo, Hitoshi
Oda, Jun'ichi
Hapten 4 was synthesized to generate catalytic antibodies triggering chemiluminescence by catalyzing the decomposition of the 1,2-dioxetane 3. The hapten 4 was so designed as to elicit a negatively charged functional group in the antibody combining site to catalyze the β-elimination of the protecting group in 3 as well as to lock the protecting group into an energetically favorable anti-periplanar conformation.
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