
Tetrahedron Letters p. 3133 - 3136 (1998)
Update date:2022-08-05
Topics:
Cave, Christian
Valancogne, Ingrid
Casas, Ramon
D'Angelo, Jean
Addition of Me2CuLi, with in situ trapping by TMSCI, to Hagemann's ester derivative 13, furnished silyl enol ether 14. Mukaiyama-type cyclization of the latter compound gave the tricyclic derivative 15, structurally related to the taxane core.
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