Mukaiyama-type, eight-membered ring closure: Access to a tricyclic system related to taxanes

DOI: 10.1016/S0040-4039(98)00461-4

Source and publish data:

Tetrahedron Letters p. 3133 - 3136 (1998)

Update date:2022-08-05

Topics:

Authors:

Cave, Christian

Valancogne, Ingrid

Casas, Ramon

D'Angelo, Jean

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4039(98)00461-4

Addition of Me₂CuLi, with in situ trapping by TMSCI, to Hagemann's ester derivative 13, furnished silyl enol ether 14. Mukaiyama-type cyclization of the latter compound gave the tricyclic derivative 15, structurally related to the taxane core.

Full text of DOI:10.1016/S0040-4039(98)00461-4

Products guided by the article

Product name:1-(6-Allyl-benzo[1,3]dioxol-5-ylmethyl)-2-methyl-4-oxo-cyclohex-2-enecarboxylic acid methyl ester

Cas No:208123-32-4

R&D Labs maybe for 208123-32-4

Onlychem (Jinan)Biotech Co.,Ltd

Contact:86-531-83175885

Address:No. 44, Honglou South Road, Jinan,China
Tianjin Ingenochem Technology Co.,Ltd

Contact:+86-22-23677060

Address:Hitech Green Industry Park K2-9-602, Nankai district
Shandong Yuanli Science and Technology Co., Ltd.

Contact:86-0536-6777557

Address:Zhuliu Industiral Park,Changle County
taicang liyuan chemical co,.ltd

website:http://www.tcliyuanchem.com/productse.php

Contact:86-512-53539583

Address:Room 804,Huaxu Building,No.95,Renmin South Road,Taicang city,Jiangsu Province,China
Nanjing HuiBaiShi Biotechnology Co.,Ltd.

Contact:+86 (25)58745219

Address:No.606 Ningliu Road,LiuHe District.

Relevant to this article

Fragment based discovery of a novel and selective PI3 kinase inhibitor

Doi:10.1016/j.bmcl.2011.07.117
(2011)
Synthese, struktur und eigenschaften neuer cyclopentadienyl oxalato-rhodiumverbindungen

Doi:10.1016/S0022-328X(97)00725-0
(1998)
Stereochemical study of the CD spectral differences between anomers of alkyl glucopyranosides

Doi:10.1016/S0957-4166(98)00037-8
(1998)
Synthesis of (benzimidazol-2-yl)aniline derivatives as glycogen phosphorylase inhibitors

Doi:10.1016/j.bmc.2016.08.069
(2016)
Diels-Alder Reactions of 2-(N-Acylamino)-1,3-dienes. Atypical Regioselectivity and Endo/Exo Selectivity

Doi:10.1021/jo980593k
(1998)
Doi:10.1021/ja00222a017
(1988)

Article Doi