Mukaiyama-type, eight-membered ring closure: Access to a tricyclic system related to taxanes

DOI: 10.1016/S0040-4039(98)00461-4

Source and publish data:

Tetrahedron Letters p. 3133 - 3136 (1998)

Update date:2022-08-05

Topics:

Authors:

Cave, Christian

Valancogne, Ingrid

Casas, Ramon

D'Angelo, Jean

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Article abstract of DOI:10.1016/S0040-4039(98)00461-4

Addition of Me₂CuLi, with in situ trapping by TMSCI, to Hagemann's ester derivative 13, furnished silyl enol ether 14. Mukaiyama-type cyclization of the latter compound gave the tricyclic derivative 15, structurally related to the taxane core.

Full text of DOI:10.1016/S0040-4039(98)00461-4

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