Protonation of Metal-Metal Bonds in Cp2Ru2(CO)3(PR3) and Cp2Mo2(CO)4(PR3)2

DOI: 10.1021/ic971516v

Source and publish data:

Inorganic Chemistry p. 2975 - 2983 (1998)

Update date:2022-07-29

Topics:

Authors:

Nataro, Chip

Angelici, Robert J.

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Article abstract of DOI:10.1021/ic971516v

Despite the much higher basicity expected for the Ru bearing the PR₃ ligand in Cp(PR₃)Ru(μ-CO)₂Ru(CO)Cp, NMR studies demonstrate that protonation of this complex with CF₃SO₃H occurs at the Ru-Ru bond,

Full text of DOI:10.1021/ic971516v

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