Tetrahedron Letters p. 3679 - 3682 (1998)
Update date:2022-08-03
Topics:
Lee, Jaemoon
Choi, Woo-Baeg
Lynch, Joseph E.
Volante
Reider
The use of cis-aminoindanol as a chiral auxiliary for asymmetric synthesis of α-amino acids is described. Alkylation of the chirally modified glycine enolate 2 with a number of alkyl halides in the presence of lithium chloride gave the corresponding alkylated product in 90 ~ 99% diastereoselectivity.
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