Synthesis of (-)-erythrodiene via intramolecular Pd-catalyzed Zn-ene reaction

DOI: 10.1016/S0040-4039(98)00991-5

Source and publish data:

Tetrahedron Letters p. 5019 - 5022 (1998)

Update date:2022-09-26

Topics:

Authors:

Oppolzer

Flachsmann

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Article abstract of DOI:10.1016/S0040-4039(98)00991-5

A highly diastereoselective synthesis of (-)-Erythrodiene was achieved via an intramolecular Pd-catalyzed Zne-ene reaction as the key step. It was found that Pd(OAc)₂/Bu₃P was a superior catalyst for this reaction to Pd(PPh₃)₄.

Full text of DOI:10.1016/S0040-4039(98)00991-5

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