Journal of Organometallic Chemistry p. 13 - 20 (1998)
Update date:2022-08-03
Topics:
Reisacher, Hans-Ulrich
Duesler, Eileen N.
Paine, Robert T.
The reactions of metallophosphenium ion complex CpW(CO)2{P(Ph)[N(SiMe3)2]} with protic reagents HBF4, HCl, and CF3COOH have been studied. The 1:1 reactions result in protonation of the W=P bond, while the 1:2 reactions display cleavage of the P-N bond. The molecular structure of one product, Cp(CO)2(Cl)WP(H)(Ph)[N(SiMe3)2], was determined by single crystal X-ray diffraction techniques: triclinic space group P1 with a=9.6732(14) A, b=11.3419(15) A, c=11.5930(14) A, α=87.724(11)°, β=77.647(11)°, γ=82.989(11)°, V=1233.0(3) A3, Z=2.
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Doi:10.1016/S0957-4166(98)00250-X
(1998)Doi:10.1080/10426509708031587
(1997)Doi:10.1002/jhet.5570440508
(2007)Doi:10.1016/S0040-4039(98)01541-X
(1998)Doi:10.1016/S0040-4020(98)00615-2
(1998)Doi:10.1021/jo980602p
(1998)
