Phosphorus, Sulfur and Silicon and the Related Elements p. 1 - 12 (1997)
Update date:2022-07-29
Topics:
Cosledan
Castel
Riviere
The lithiation of Mes2GeH2 with nBuLi in a 1:2 molar ratio at low temperature gives an aggregate 1 of the parent germyllithiated derivative, unreacted nBuLi and ether in a 1:1:1 ratio. Compound 1 was characterized by 1H, 13C and 7Li NMR. Reactions of 1 with D2O and Me3SiCl afford exclusively the monosubstituted derivatives. With PhCHO, we observe the formation of the germylated alcohol 5 and PhCHOHBu. Reaction with Mel is more complex and leads to the dimethylated compound 6 through a single electron transfer mechanism. Transient radical species are detected by an ESR study.
Jinhua City Mingzhu Pharmaceutical Co.,Ltd.
Contact:15857995878 0579-82207761
Address:No.169 Shenze Road, New Area,Jinpan Development Zone, Jinhua
Lishui Nanming Chemical Co., Ltd(expird)
Contact:+86-0578-2134101，2697830
Address:No.19 Tongji Road Shuige Industrial zone
Fusilin chemical science & technology co., ltd.
Contact:532-80698166/86057573, +86-400-669-7885
Address:School of Material Science & Engineering, Shandong Uinversity of Science & Technology, Huangdao Zone, Qindao, Shandong
Suzhou Wedo Chemicals Co., Ltd.
Contact:86 512 58100425
Address:Zonger Road, DongSha Industry Park , Zhangjiagang, Jiangsu, China
shandong zhongke taidou chemical co.,ltd
Contact:86-531-88682301
Address:Jinan shandong Province CHina
Doi:10.1021/jo981477k
(1999)Doi:10.1002/hc.21273
(2015)Doi:10.1021/jf980265l
(1999)Doi:10.1039/a807448h
(1998)Doi:10.1016/S0040-4039(98)02203-5
(1998)Doi:10.1016/S0040-4020(02)00370-8
(2002)
