Phosphorus, Sulfur and Silicon and the Related Elements p. 1 - 12 (1997)
Update date:2022-07-29
Topics:
Cosledan
Castel
Riviere
The lithiation of Mes2GeH2 with nBuLi in a 1:2 molar ratio at low temperature gives an aggregate 1 of the parent germyllithiated derivative, unreacted nBuLi and ether in a 1:1:1 ratio. Compound 1 was characterized by 1H, 13C and 7Li NMR. Reactions of 1 with D2O and Me3SiCl afford exclusively the monosubstituted derivatives. With PhCHO, we observe the formation of the germylated alcohol 5 and PhCHOHBu. Reaction with Mel is more complex and leads to the dimethylated compound 6 through a single electron transfer mechanism. Transient radical species are detected by an ESR study.
CHANGYI CITY FENGRUN FINE CHEMICAL CO.,LTD
website:http://www.fengrunhuagong.com
Contact:+86-536-7869976
Address:Changyi Coastal Economic Development Zone
Anhui New Star Pharmaceutical Development Co., Ltd
Contact:013956922763
Address:Floor 3, F9A, F Workshop, No.110 Kexue Road, High-Tech Development Zone, Hefei, Anhui ,China
Feis International Trade Co,. Ltd
Contact:13961823444-18235944442
Address:Wuxi jiangsu
Longhui qunfeng Chemical Co., Ltd
Contact:86-731-82173407
Address:South-east Industrial Park, Longhui County, Hunan Province, China
Sichuan Sangao Biochemical Co., Ltd
Contact:+86-28-84874233
Address:19F, Bldg.2, Shudu Center, Tianfu 2nd St., Hi-tech zone, Chengdu 610041, Sichuan Province, China.
Doi:10.1021/jo981477k
(1999)Doi:10.1002/hc.21273
(2015)Doi:10.1021/jf980265l
(1999)Doi:10.1039/a807448h
(1998)Doi:10.1016/S0040-4039(98)02203-5
(1998)Doi:10.1016/S0040-4020(02)00370-8
(2002)
