Phosphorus, Sulfur and Silicon and the Related Elements p. 1 - 12 (1997)
Update date:2022-07-29
Topics:
Cosledan
Castel
Riviere
The lithiation of Mes2GeH2 with nBuLi in a 1:2 molar ratio at low temperature gives an aggregate 1 of the parent germyllithiated derivative, unreacted nBuLi and ether in a 1:1:1 ratio. Compound 1 was characterized by 1H, 13C and 7Li NMR. Reactions of 1 with D2O and Me3SiCl afford exclusively the monosubstituted derivatives. With PhCHO, we observe the formation of the germylated alcohol 5 and PhCHOHBu. Reaction with Mel is more complex and leads to the dimethylated compound 6 through a single electron transfer mechanism. Transient radical species are detected by an ESR study.
Xi'an caijing Opto-Electrical Science & Technology Co., LTD
Contact:+86-29-88294447
Address:NO.168 Zhangba Rd. East, Xi'an, P.R.China
Lanzhou huibang biological chemical technology Co., LTD
Contact:0931-7843964
Address:NO.2011,Yannan Road,Chengguan,
Contact:0792-8228321
Address:10TH Floor No.121 binjiang Road Xunyang District
Nanjing Legend Pharmaceutical & Chemical Co., Ltd.
Contact:+86-25-83767696
Address:14-7 Zhongshan Lu Guluo District, Nanjing
Contact:
Address:308# dongwu avenue dongxihu district wuhan city
Doi:10.1021/jo981477k
(1999)Doi:10.1002/hc.21273
(2015)Doi:10.1021/jf980265l
(1999)Doi:10.1039/a807448h
(1998)Doi:10.1016/S0040-4039(98)02203-5
(1998)Doi:10.1016/S0040-4020(02)00370-8
(2002)
