Tetrahedron p. 3327 - 3336 (1999)
Update date:2022-08-03
Topics:
Curran, Dennis P.
Gabarda, Ana E.
Reduction of 2-substituted 1,3-diiodopropane derivatives with tin hydride provides substituted cyclopropanes. The reaction occurs through a homolytic substitution of the 3-iodopropyl radical, which has a rate constant of about 5 x 105 s-1 at 80°C.
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