Palladium"II# complexes of hybrid phosphine
2958
REFERENCES
62[1 "s\ C4H3# ^ 62[2 "d\ JPÐC ꢁ 0[6 Hz\ C4H3# ^ 62[4
"d\ JPÐC ꢁ 0[6 Hz\ C4H3# ^ 017[1 "d\ JPÐC ꢁ 00[9
Hz\ m!C5H4PCp# ^ 017[3 "d\ JPÐC ꢁ 05[6 Hz\ m!
C5H4P"O#Cp# ^ 020[2 "s\ p!C5H4PCp# ^ 020[3 "s\ p!
C5H4P"O#Cp# ^ 020[3 "d\ JPÐC ꢁ 8[6 Hz\ o!
C5H4PCp# ^ 022[3 "d\ JPÐC ꢁ 08[6 Hz\ o!
C5H4P"O#Cp# ^ 023[4 "d\ JPÐC ꢁ 094[5 Hz\ q!
C5H4PCp# ^ 027[7 "d\ JPÐC ꢁ 09[7 Hz\ q!
C5H4P"O#Cp#[ 20P NMR "CDCl2\ 19>C#\ d ]
−05[6 "s\ 0P\ CpPPh1# ^ 17[4 "s\ 0P\ CpP"O#Ph1#[
Anal ] Calcd for C57H47Fe1O2P3 "C23H17FeO!
P1 = 9[4H1O# ] C\ 69[4 ^ H\ 4[9[ Found ] C\ 69[6 ^ H\
0[ "a# Grim\ S[ O[ and Mitchell\ J[ D[\ Synth[ React[
Inor`[ Met[!Or`[ Chem[\ 0863\ 3\ 110 ^ "b# Grim\
S[ O[\ Satek\ L[ C[\ Tolman\ C[ A[ and Jesson\ J[
P[\ Inor`[ Chem[\ 0864\ 03\ 545 ^ "c# Grim\ S[ O[
and Mitchell\ J[ D[\ Inor`[ Chem[\ 0866\ 05\ 0651 ^
"d# Grim\ S[ O[\ Smith\ P[ H[\ Colquhoun\ I[ J[
and McFarlane\ W[\ Inor`[ Chem[\ 0879\ 08\ 0284 ^
"e# Grim\ S[ O[ and Walton\ E[ D[\ Inor`[ Chem[\
0879\ 08\ 0871 ^ "f# Colquhoun\ I[ J[\ Grim\ S[ O[
and McFarlane\ W[\ Inor`[ Chem[\ 0870\ 19\ 1405[
1[ Uson\ R[\ J[ Chem[ Soc[\ Dalton Trans[\ 0868\ 62[
2[ Kabachnik\ M[ I[\ Medved|\ T[ Ya[\ Pisareva\ S[
A[\ Ignat|eva\ T[ I[\ Lomakina\ L[ N[\ Koza!
chenko\ A[ G[\ Matrosov\ E[ I[\ Petrovskii\ P[ V[
and Komarova\ M[ P[\ Izv[ Akad[ Nauk SSSR\
Ser[ Khim[\ 0879\ 562 ^ Bull Acad[ Sci[ USSR\ Div[
Chem[ Sci[ "En`lish Transl[# 0879\ 384[
3[ Hall\ S[ R[\ Skelton\ B[ W[ and White\ A[ H[\
Aust[ J[ Chem[\ 0872\ 25\ 156[
4[ Wegman\ R[ W[\ Abatjoglou\ A[ G[ and Harrison\
A[ M[\ J[ Chem[ Soc[\ Chem[ Commun[\ 0876\
0780[
5[ Higgins\ S[ J[\ Shaw\ B[ L[ and Taylor\ R[\ J[
Or`anomet[ Chem[\ 0876\ 214\ 174[
6[ Berry\ D[ E[\ Browning\ J[\ Dixon\ K[ R[ and
Hilts\ R[ W[\ Can[ J[ Chem[\ 0877\ 55\ 0161[
7[ Bond\ A[ M[\ Colton\ R[ and Pangiotidou\ P[\
Or`anometallics 0877\ 6\ 0656[
8[ Bakar\ M[ A[\ Hills\ A[\ Hughes\ D[ L[ and Leigh\
G[ J[\ J[ Chem[ Soc[\ Dalton Trans[\ 0878\ 0306[
09[ Terekhova\ M[ I[\ Kron\ T[ E[\ Bondarenko\ N[
A[\ Petrov\ E[ S[ and Tsvetkov\ E[ N[\ Izv[ Akad[
Nauk SSSR\ Ser[ Khim[\ 0880\ 1992 ^ Bull[ Acad[
Sci[ USSR\ Div[ Chem[ Sci[ "En`lish Transl[# 0880\
0444[
00[ Kron\ T[ E[\ Sobolev\ A[ N[\ Terekhova\ M[ I[\
Bondarenko\ N[ A[\ Petrov\ E[ S[ and Tsvetkov\
E[ N[\ Koord[ Khim[\ 0881\ 07\ 092 ^ Coord[ Chem[
"En`lish Transl[# 0881\ 07\ 78[
01[ Davies\ J[ A[\ Pinkerton\ A[ A[ and Vilmer\ M[\
Acta Cryst[ C[\ 0881\ 37\ 0916[
02[ Visseaux\ M[\ Dormond\ A[ and Baudry\ D[\ Bull[
Soc[ Chim[ Fr[\ 0882\ 029\ 062[
03[ Blagborough\ T[ C[\ Davis\ R[ and Ivison\ P[\ J[
Or`anomet[ Chem[\ 0883\ 356\ 74[
04[ Al!Jibori\ S[ A[\ Kalay\ Z[ M[ and Al!Allaf\ T[ A[
K[\ Transition Metal Chem[\ 0883\ 08\ 182[
05[ Anderson\ G[ K[ and Cross\ R[ J[\ Chem[ Soc[
Rev[\ 0879\ 8\ 074[
4[9 ^ "b# Although dppfcO itself is
a new
compound\ its rhenium ð08cŁ and tungsten ð08dŁ
complexes have been reported and structurally
characterized[ The Re and W complexes were
obtained by the oxidation of the corresponding
dppfc metal derivatives with H1O1 ^ "c# Hor\ T[ S[
A[\ Chan\ H[ S[ O[\ Tan\ K[!L[\ Phang\ L[!T[\
Yan\ Y[ K[\ Liu\ L[!K[ and Wen\ L[!K[\ Poly!
hedron\ 0880\ 09\ 1326 ^ "d# Hsu\ S[ C[ N[\ Yeh\
W[!Y[ and Chiang\ M[ Y[\ J[ Or`anomet[ Chem[\
0884\ 381\ 010[
19[ Ebsworth\ E[ A[ V[\ Rankin\ D[ W[ H[ and
Cradock\ S[\ Structural Methods in Inor`anic
Chemistry[ Blackwell Scienti_c Publications\
Oxford\ 0876[
10[ "a# Ferguson\ G[\ McCrindle\ R[\ McAlees\ A[ J[
and Parvez\ M[\ Acta Crystallo`r[ B\ 0871\ 27\
1568 ^ "b# Kitano\ Y[\ Kinoshita\ Y[\ Nakamura\
R[ and Ashida\ T[\ Acta Crystallo`r[ C\ 0872\ 28\
0904[
11[ Bertseh!Frank\ B[ and Frank\ W[\ Acta Crys!
tallo`r[ C\ 0885\ 41\ 217[
12[ "a# A weak solid state Pd= = =FBF2 interaction
"1[124"4# _# has been reported ð12bŁ ^ "b# Rhein!
gold\ A[ L[\ Wu\ G[ and Heck\ R[ F[\ Inor`[ Chim[
Acta\ 0876\ 020\ 036[
13[ "a# Gilje\ J[ W[ and Roesky\ H[ W[\ Chem[ Rev[\
0883\ 83\ 784 and references cited therein ^ "b#
Grushin\ V[ V[ and Alper\ H[\ Or`anometallics\
0882\ 01\ 0789 ^ "c# Driver\ M[ S[ and Hartwig\
J[ F[\ J[ Am[ Chem[ Soc[\ 0885\ 007\ 3195 ^ "d#
Kuznetsov\ V[ F[\ Bensimon\ C[\ Facey\ G[ A[\
Grushin\ V[ V[ and Alper\ H[\ Or`anometallics\
0886\ 05\ 86[
14[ "a# Oldham\ C[ In Comprehensive Coordination
Chemistry\ Vol[ 1\ Chapter 04[5\ ed[ G[ Wilk!
inson[ Pergamon Press\ Oxford\ 0876\ p[ 324 and
references cited therein ^ "b# Barnard\ C[ F[ G[ and
Russell\ M[ J[ H[ In Comprehensive Coordination
Chemistry\ Vol[ 4\ Chapter 40\ ed[ G[ Wilkinson[
Pergamon Press\ Oxford\ 0876\ p[ 0988 and ref!
erences cited therein ^ "c# Ruiz\ J[\ Cutillas\ N[\
06[ "a# Berners!Rice\ S[ J[\ Johnson\ R[ J[\ Mirabelli\
C[ K[\ Faucette\ L[ F[\ McCabe\ F[ L[ and Sadler\
P[ J[\ Inor`[ Chem[\ 0876\ 15\ 2272 ^ "b# Mason\
M[ R[ and Verkade\ J[ G[\ Or`anometallics\ 0881\
00\ 1101 ^ "c# Grushin\ V[ V[\ 0884\ unpublished
results[
07[ Prepared by the recently developed\ novel cata!
lytic method for the synthesis of BPMOs ]
Grushin\ V[ V[\ unpublished results "0884Ð0885# ^
Patent application has been _led[
Torregrosa\ J[\ Garcia\ G[\ Lopez\ G[\ Chaloner\
ꢂ
P[ A[\ Hitchcock\ P[ B[ and Harrison\ R[ M[\
J[ Chem[ Soc[\ Dalton Trans[\ 0883\ 1242 ^ "d#
Grushin\ V[ V[\ Bensimon\ C[ and Alper\ H[\
Or`anometallics\ 0884\ 03\ 2148 ^ "e# Grushin\ V[
V[ and Alper\ H[\ J[ Am[ Chem[ Soc[\ 0884\ 006\
3294[
0H
15[ Cotton\ F[ A[ and Wilkinson\ G[\ Advanced Inor!
`anic Chemistry\ 4th edn[ John Wiley and Sons\
New York\ 0877[
08[ "a# Spectral and analytical data for dppfcO ]
NMR "CDCl2\ 19>C#\ d ] 3[9 "m\ 1H\ Cp# ^ 3[1 "m\
1H\ Cp# ^ 3[3 "m\ 1H\ Cp# ^ 3[5 "m\ 1H\ Cp# ^ 6[0Ð
6[6 "m\ 19H\ Ph#[ 02C NMR "CDCl2\ 19>C#\ d ] 16[ "a# Seyferth\ D[\ US Patent 2\315\910\ 0858 ^ "b#
61[8 "s\ C4H3# ^ 62[9 "s\ C4H3# ^ 62[0 "s\ C4H3# ^
Abatjoglou\ A[ G[ and Kapicak\ L[ A[\ US Patent