Novel cage polycarbosilanes. Preparation and characterization of dodecamethyl-2,3,5,6,7,8-hexasilabicyclo[2.2.2]octane and its derivatives

DOI: 10.1246/cl.1998.1145

Source and publish data:

Chemistry Letters p. 1145 - 1146 (1998)

Update date:2022-08-04

Topics:

Authors:

Shimizu, Masaki

Inamasu, Naoko

Nishihara, Yasushi

Hiyama, Tamejiro

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Article abstract of DOI:10.1246/cl.1998.1145

2,2,3,3,5,5,6,6,7,7,8,8-Dodecamethyl-2,3,5,6,7,8-hexasilabicyclo[2.2.2] octane (1) was synthesized for the first time via three steps in 56% overall yield through triple silylation with three dichlorodimethyldisilane molecules of two trianionic molecules

Full text of DOI:10.1246/cl.1998.1145

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