Facile and efficient preparation of a C-1 side chain equivalent of zaragozic acid C

DOI: 10.1248/cpb.46.1816

Source and publish data:

Chemical and Pharmaceutical Bulletin p. 1816 - 1819 (1998)

Update date:2022-08-04

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Authors:

Sato, Hiroki

Kitaguchi, Jun-Ichi

Nakamura, Sei-Ichi

Hashimoto, Shun-Ichi

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Article abstract of DOI:10.1248/cpb.46.1816

An optically pure C-1 side chain equivalent of zaragozic acid C, (4R,5R)-4-benzyloxy-5-methyl-6-phenyl-1-hexyne, has been synthesized in ten steps from (E)-4-phenyl-2-buten-1-ol with an overall yield of 50%, involving a Sharpless asymmetric epoxidation as

Full text of DOI:10.1248/cpb.46.1816

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