Bulletin of the Academy of Sciences of the USSR Division of Chemical Science p. 1849 - 1853 (1991)
Update date:2022-07-29
Topics:
Burgart, Ya. V.
Skryabina, Z. E.
Saloutin, V. I.
Depending on the nature of the dicarbonyl fragment, the reaction of fluorinated copper(II) bis(1,3-diketonates) with ethylenediamine and its monoprotonated salts under mild conditions gives N,N'-ethylenebis(aminovinyl ketones) and/or 1,4-diazepines.In excess ethylenediamine, copper(II) and nickel(II) N,N'-ethylenebis(aminovinyl ketonates) undergo cyclization to 1,4-diazepines.
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