New nucleoside heteroanalogues: Desoxynucleoside selenocyanates

DOI: 10.1016/S0040-4039(98)02559-3

Source and publish data:

Tetrahedron Letters p. 1181 - 1184 (1999)

Update date:2022-08-04

Topics: Nucleoside

Authors:

Belostotskii

Lexner Lexner

Hassner Hassner

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Article abstract of DOI:10.1016/S0040-4039(98)02559-3

New nucleoside heteroanalogues, 5' and 3'-desoxynucleoside selenocyanates and primary desoxysugar selenocyanates, were synthesized from activated nucleoside and sugar derivatives and a new convenient seleno nucleophile, tetrabutylammonium selenocyanate. Tresylate-based activation of hydroxy functions turned out to be most successful for formation of theme selenocyanates compared with mesylate- or triflate-based activation.

Full text of DOI:10.1016/S0040-4039(98)02559-3

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