Tetrahedron Letters p. 1181 - 1184 (1999)
Update date:2022-08-04
Topics: Nucleoside
Belostotskii
Lexner
Hassner
New nucleoside heteroanalogues, 5' and 3'-desoxynucleoside selenocyanates and primary desoxysugar selenocyanates, were synthesized from activated nucleoside and sugar derivatives and a new convenient seleno nucleophile, tetrabutylammonium selenocyanate. Tresylate-based activation of hydroxy functions turned out to be most successful for formation of theme selenocyanates compared with mesylate- or triflate-based activation.
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