SILICON-PHOSPHORUS ANALOGIES. RATE CONTROLLING FACTORS IN SN2(P) REACTIONS. INFLUENCE OF THE NUCLEOPHILE FOR A GIVEN STEREOCHEMISTRY.

DOI: 10.1016/S0040-4039(00)88331-8

Source and publish data:

Tetrahedron Letters p. 4323 - 4326 (1983)

Update date:2022-08-03

Topics:

Authors:

Corriu, Robert J.P.

Lanneau, Gerard F.

Leclercq, Dominique

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Article abstract of DOI:10.1016/S0040-4039(00)88331-8

S_N2(P) reactions of chlorophosphates, which take place with inversion of configuration, are higly dependent upon the nature of the nucleophile.On the contrary, exocyclic substitutions of five-membered ring chlorophosphates with retention show a marked kinetic levelling effect.

Full text of DOI:10.1016/S0040-4039(00)88331-8

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