Synthesis of new atropisomeric bisphosphine ligands bearing chiral phospholane and their use in asymmetric hydrogenation

DOI: 10.1248/cpb.47.436

Source and publish data:

Chemical and Pharmaceutical Bulletin p. 436 - 439 (1999)

Update date:2022-08-04

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Authors:

Fujie, Naoto

Matsui, Manko

Achiwa, Kazuo

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Article abstract of DOI:10.1248/cpb.47.436

Novel chiral bisphosphine ligands bearing (2S,5S)-dimethylphospholano group on a chiral biphenyl back-bone were designed and prepared. Asymmetric hydrogenations of a ketone and an olefin with the rhodium(I) complex catalysts prepared in situ from [Rh(COD)

Full text of DOI:10.1248/cpb.47.436

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