BEITRAEGE ZUR CHEMIE DES IODOPENTAFLUORIDS. TEIL IV. IF5 EIN SELEKTIVES OXIDATIVES FLUORIERUNGSMITTEL FUER ORGANOPHOSPHOR(III)-VERBINDUNGEN

DOI: 10.1016/S0022-1139(00)81928-4

Source and publish data:

Journal of Fluorine Chemistry p. 73 - 82 (1986)

Update date:2022-08-05

Topics:

Authors:

Frohn, H. J.

Maurer, H.

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Article abstract of DOI:10.1016/S0022-1139(00)81928-4

Aryl-and alkylphosphines R3P, R2PF, R2PCl, and RPCl2 are oxidized by IF5 to the corresponding fluorophosphoranes in a fast one step-reaction at or below 0 deg C.The only coproduct is elemental iodine.IF3 or IF as reduction products of IF5 are not observed.Fission of P-C - bonds by from I2 and IF5 is negligible under reaction conditions.In alkylfluorophosphoranes fluoride donor-acceptor-interactions between fluorophosphoranes and IF5 are observed.

Full text of DOI:10.1016/S0022-1139(00)81928-4

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