Journal of the Chemical Society, Dalton Transactions p. 3127 - 3132 (1991)
Update date:2022-08-03
Topics:
Brisdon, Alan K.
Holloway, John H.
Hope, Eric G.
Townson, Paul J.
Levason, William
Ogden, J. Steven
Five high-oxidation-state metal oxide fluorides, MnO3F, ReO3F, ReO2F3, ReOF5 and ReOF4 have been isolated as molecular species in inert-gas matrices at low temperatures, and studied by IR and UV/VIS spectroscopy.In particular, the electronic spectra are described and the principal charge-transfer bands assigned using the optical electronegativity model.This suggested that a new value for χopt(F-) of 3.6 is appropriate for transition-metal oxide fluorides.
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