Control of diastereoselectivity in metal-catalyzed 1,3-dipolar cycloaddition between diphenylnitrone and chiral auxiliary-substituted crotonyl amide

DOI: 10.1016/S0040-4020(99)00469-X

Source and publish data:

Tetrahedron p. 8509 - 8524 (1999)

Update date:2022-08-04

Topics:

Authors:

Desimoni, Giovanni

Faita, Giuseppe

Mella, Mariella

Righetti, Pierpaolo

Zema, Michele

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Article abstract of DOI:10.1016/S0040-4020(99)00469-X

The 1,3-dipolar cycloaddition (1,3-DC) between diphenyl nittone (1) and 4-(S)benzyl-((E)-2'-butenoyl)-1,3-oxazolidin-2-one (2) was studied in the presence of several inorganic salts whose cations behave as Lewis acid. Depending on the salt and the experim

Full text of DOI:10.1016/S0040-4020(99)00469-X

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Product name:(3'R,4S,4'S,5'R)-4-benzyl-3-((5'-methyl-2',3'-diphenylisoxazolidin-4'-yl)carbonyl)-1,3-oxazolidin-2-one

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