Tetrahedron Letters p. 5763 - 5766 (1999)
Update date:2022-09-26
Topics: Enantioselective synthesis Diastereoselective Michael addition Sulfoxide
Acherki, Hassan
Alvarez-Ibarra, Carlos
Barrasa, Alicia
De Dios, Alfonso
Diastereoselective reactions of suitably functionalized homochiral β-iminosulfoxides with Michael acceptors provide a new and efficient route for the asymmetric synthesis of C-4 substituted 2-pyroaminoadipates. Extension of the scope of the sulfoxide-mediated aza-enolate conjugate addition (Hua's reaction) has also been explored.
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