Stereoselectivity, periselectivity and regioselectivity in the intramolecular cycloadditions of heptafulvene-fulvenes

DOI: 10.1016/S0040-4020(99)00489-5

Source and publish data:

Tetrahedron p. 9171 - 9184 (1999)

Update date:2022-08-04

Topics:

Authors:

Liu, Ching-Yang

Shie, Huei-Yan

Yu, Chien-Liang

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Article abstract of DOI:10.1016/S0040-4020(99)00489-5

The side-chain and substituent control of stereoselectivity, periselectivity and regioselectivity in the intramolecular [8 + 6] and [4 + 2] cycloadditions of electron-deficient 8-cyanoheptafulvenes connected at C- 8 by trimethylene or tetramethylene chains to C-6 of electron-rich 6-methyl- or 6-phenylfulvenes are discussed.

Full text of DOI:10.1016/S0040-4020(99)00489-5

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