Nitrene-Transfer Reaction between Azide and Unsaturated Ether in the Presence of Pd(II) Catalyst

DOI: 10.1246/bcsj.61.931

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Bulletin of the Chemical Society of Japan p. 931 - 938 (1988)

Update date:2022-08-04

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Authors:

Migita, Toshihiko

Hongoh, Kazuya

Naka, Hiroyuki

Nakaido, Setsuko

Kosugi, Masanori

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Article abstract of DOI:10.1246/bcsj.61.931

Azidoformate reacted with allylic ethers to give 1-alkoxy-1-(alkoxycarbonylimino)alkane under catalysis by PdCl2(PhCN)2.The same imines were formed almost quantitatively by noncatalyzed reaction of the azide with the corresponding vinylic ethers.The rate

Full text of DOI:10.1246/bcsj.61.931

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