Synthesis of vinyl spirolactones and lactams by sequential cross- coupling metathesis, [2+2] photocycloaddition and cyclobutane ring-opening

DOI: 10.1016/S0040-4039(99)01173-9

Source and publish data:

Tetrahedron Letters p. 6001 - 6004 (1999)

Update date:2022-08-03

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Authors:

Faure, Sophie

Blanc, Sylvie Piva-Le

Piva, Olivier

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Article abstract of DOI:10.1016/S0040-4039(99)01173-9

Unsaturated oxoesters and amides have been submitted to cross-coupling metathesis with trimethylallylsilane using Grubbs' catalyst. The resulting allylsilanes underwent, under irradiation, intramolecular [2+2] photocycloaddition leading to trimethylsilylm

Full text of DOI:10.1016/S0040-4039(99)01173-9

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