Tetrahedron Letters p. 1303 - 1306 (1998)
Update date:2022-08-02
Topics:
Marshall, James A.
Hinkle, Kevin W.
The total synthesis of (+)-(30S)-bullanin, a highly cytotoxic Annonaceous acetogenin, was effected by a convergent approach in which the key core bis-2,2'-tetrahydrofuran stereocenters were introduced through a combination of Sharpless asymmetric dihydroxylation and S(E)2' additions of oxygenated nonracemic allylic stannane and indium reagents to γ-oxygenated aldehydes.
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